Search results for "4]oxazepines"

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Organocatalytic enantioselective Strecker reaction with seven-membered cyclic imines

2018

[EN] A highly enantioselective Strecker reaction with dibenzo[b,f][1,4]oxazepines has been described using a dihydroquinine-derived thiourea as organocatalyst. The reaction affords chiral 10,11-dihydrodibenzo[b,f][1,4] oxazepine 11-carbonitrile derivatives in excellent yields (up to 99%) and excellent enantioselectivities (up to 98%) under mild reaction conditions.

010405 organic chemistryChemistryOrganocatalysisDibenzo[bf][14]oxazepinesStrecker amino acid synthesisEnantioselective synthesisGeneral Chemistry010402 general chemistry01 natural sciences0104 chemical sciencesReaccions químiquesAlpha-amino nitrilesCatàlisiStrecker reactionOrganocatalysisFISICA APLICADAAsymmetric catalysisEconomic historymedia_common.cataloged_instanceEuropean unionmedia_common

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